Article 9 Making Potassium Chlorate The following is an excerpt from The Jolly Roger's book on explosives: ----------------------------------------------------------------------------- Making Plastic Explosives from Bleach by The Jolly Roger Potassium chlorate is an extremely volatile explosive compound, and has been used in the past as the main explosive filler in grenades, land mines, and mortar rounds by such countries as France and Germany. Common household bleach contains a small amount of potassium chlorate, which can be extracted by the procedure that follows. First off, you must obtain: [1] A heat source (hot plate, stove, etc.) [2] A hydrometer, or battery hydrometer [3] A large Pyrex, or enameled steel container (to weigh chemicals) [4] Potassium chloride (sold as a salt substitute at health and nutrition stores) Take one gallon of bleach, place it in the container, and begin heating it. While this solution heats, weigh out 63 grams of potassium chloride and add this to the bleach being heated. Constantly check the solution being heated with the hydrometer, and boil until you get a reading of 1.3. If using a battery hydrometer, boil until you read a FULL charge. Take the solution and allow it to cool in a refrigerator until it is between room temperature and 0 degrees Celcius. Filter out the crystals that have formed and save them. Boil this solution again and cool as before. Filter and save the crystals. Take the crystals that have been saved, and mix them with distilled water in the following proportions: 56 grams per 100 milliliters distilled water. Heat this solution until it boils and allow to cool. Filter the solution and save the crystals that form upon cooling. This process of purification is called "fractional crystalization". These crystals should be relatively pure potassium chlorate. Powder these to the consistency of face powder, and heat gently to drive off all moisture. Now, melt five parts Vaseline with five parts wax. Dissolve this in white gasoline (camp stove gasoline), and pour this liquid on 90 parts potassium chlorate (the powdered crystals from above) into a plastic bowl. Knead this liquid into the potassium chlorate until intimately mixed. Allow all gasoline to evaporate. Finally, place this explosive into a cool, dry place. Avoid friction, sulfur, sulfides, and phosphorous compounds. This explosive is best molded to the desired shape and density of 1.3 grams in a cube and dipped in wax until water proof. These block type charges guarantee the highest detonation velocity. Also, a blasting cap of at least a 3 grade must be used. The presence of the afore mentioned compounds (sulfur, sulfides, etc.) results in mixtures that are or can become highly sensitive and will possibly decompose explosively while in storage. You should never store homemade explosives, and you must use EXTREME caution at all times while performing the processes in this article. ----------------------------------------------------------------------------- I have two words for this article: BULL SHIT! Mixing Potassium Chloride with Bleach is NOT going to give you Potassium Chlorate. I tried it myself with precise scrutiny and it did not work. I tried it several times, and still it did not work. Now, mixing Potassium Chloride with Sodium Hypochlorite (the principle ingredient in bleach) does form Potassium Chlorate when heated EXTREMELY hot. But the probelm is that you need potassium chloride solid, and sodium hypochlorite solid too, so you'll have to dehydrate the bleach. The next problem is that the Potassium Chloride and the Sodium Hypochlorite must be heated together at high temperature. What will happen though is that you can't tell when the two have completed the reaction, and it you let them heat for too long, they'll form Potassium chlorate, the Potassium chlorate will ignite and form Potassium Chloraide again! Basically, I say don't waste your time with this process. I will look around and see if I can't come up with a better idea to make this stuff. Or you could call around to some chem supply places (Chemfil Canada I believe will supply this stuff) and just buy it! If they ask what it is for, tell them it's for your chemistry set or something and you want it to experiment with Stoichiometry :) Or if you don't want to do that, steal some from your Chem lab! :)